One-Step Synthesis of 1,4-Diketones by Nucleophilic Reaction to Tricarbonyl Complexes of α,β-Unsaturated Ketones

DOI: 10.1246/bcsj.61.3362

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3362 - 3364 (1988)

Update date:2022-08-04

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Authors:

Kitahara, Haruo

Tozawa, Yasuyuki

Fujita, Seikou

Tajiri, Akio

Morita, Noboru

Asao, Toyonobu

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Article abstract of DOI:10.1246/bcsj.61.3362

Tricarbonyliron complexes of 3-buten-2-one, 3-penten-2-one, and 4-phenyl-3-buten-2-one reacted with organolithium and Grignard reagents to afford 1,4-diketones in one step, some of the products are amenable to convertion to natural products.

Full text of DOI:10.1246/bcsj.61.3362

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