Biomimetic Cyclization of Ambliofuran and Analog By Using Mercury(II) Triflate/N,N-Dimethylaniline Complex: Synthesis of (+/-)-Ambliol-A

DOI: 10.1016/S0040-4039(00)83973-8

Source and publish data:

Tetrahedron Letters p. 187 - 190 (1986)

Update date:2022-09-26

Topics:

Authors:

Nishizawa, Mugio

Yamada, Hidetoshi

Hayashi, Yuji

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Article abstract of DOI:10.1016/S0040-4039(00)83973-8

Biomometic cyclization of ambliofuran with mercury(II) triflate/N,N-dimethylaniline complex is initiated from the internal double bound (Δ⁷) in high selectivity, whereas the corresponding sulfone is cyclized from terminal (Δ¹⁵) olefin to give marginatan skeleton.

Full text of DOI:10.1016/S0040-4039(00)83973-8

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