Stereoselective Synthesis of Quaternary Carbon Centres

DOI: 10.1039/c39860000495

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 495 - 496 (1986)

Update date:2022-09-26

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Authors:

Davies, Stephen G.

Walker, Jonathan C.

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Article abstract of DOI:10.1039/c39860000495

α-Alkyl-α,β-unsaturated acyl ligands attached to the chiral auxiliary <(η⁵-C5H5)Fe(CO)(PPh3)> undergo Michael additions to generate the corresponding E-enolates which on alkylation produce quaternary carbon centres stereoselectively.

Full text of DOI:10.1039/c39860000495

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Product name:Fe(C₅H₅)(CO)(C(O)C(CH₂)CH₃)(P(C₆H₅)3)

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