Stereoselective Synthesis of Quaternary Carbon Centres

DOI: 10.1039/c39860000495

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 495 - 496 (1986)

Update date:2022-09-26

Topics:

Authors:

Davies, Stephen G.

Walker, Jonathan C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39860000495

α-Alkyl-α,β-unsaturated acyl ligands attached to the chiral auxiliary <(η⁵-C5H5)Fe(CO)(PPh3)> undergo Michael additions to generate the corresponding E-enolates which on alkylation produce quaternary carbon centres stereoselectively.

Full text of DOI:10.1039/c39860000495

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Fe(C₅H₅)(CO)(C(O)C(CH₂)CH₃)(P(C₆H₅)3)

Cas No:105813-64-7

R&D Labs maybe for 105813-64-7

Tianjin Ingenochem Technology Co.,Ltd

Contact:+86-22-23677060

Address:Hitech Green Industry Park K2-9-602, Nankai district
Binzhou Holly Pharmaceutical Co.,Ltd.

Contact:74517

Address:No.15 Dapu Road,Huangpu District Shanghai,P.R.China
Chiral Quest (Suzhou) Company Ltd

website:http://www.chiralquest.com

Contact:+86-0512-62956066

Address:B1/9, 218 Xinghu Street, Suzhou Industrial Park
ALPHA PHARMACEUTICAL CO，LTD JIANGSU

Contact:+86-527-84829968,+86-527-84829998

Address:suqian city
Shandong Yubin Chemical CO.,LTD

website:http://www.yukaichem.com/en.html

Contact:+86-536-8865336

Address:binhai economic development zone，262737 shangdong，china

Relevant to this article

Discrete and well-defined hydrophobic phases confined in self-assembled spherical complexes

Doi:10.1002/anie.200801700
(2008)
Synthesis and application of alkenylstannanes derived from base-sensitive cyclopropenes

Doi:10.1021/ol801486v
(2008)
Reactions of N- and C-alkenylanilines: VIII. Synthesis of functionalized cycloalka[b]indoles from o-(cycloalk-2-en-1-yl)anilines

Doi:10.1134/S1070428007090096
(2007)
Synthesis of seven- and eight-membered [1,2-a] alicyclic ring-fused benzimidazoles and 3-aziridinylazepino[1,2-a]benzimidazolequinone as a potential antitumour agent

Doi:10.1016/j.tetlet.2008.06.121
(2008)
Manganese-catalyzed synthesis of hydantoin derivatives from terminal alkynes and isocyanates

Doi:10.1246/cl.2008.740
(2008)
Radiation-induced formation of purine 5′,8-cyclonucleosides in isolated and cellular DNA: High stereospecificity and modulating effect of oxygen

Doi:10.1039/c004531d
(2010)

Article Doi