Tetrahedron Letters p. 1673 - 1676 (1986)
Update date:2022-09-26
Topics:
Hafner, Klaus
Knaup, Guenter L.
Thermolysis of dimethyl 1,2-heptalenedicarboxylates 1 leads by two different pathways to the corresponding 1,3-dicarboxylates 2 and to azulenes 3 - 5.The rearrangement of 1 into 2 presumably proceeds via a heptvalene intermediate 10.
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