DI-TERT-BUTYLMETHYLSILYL (DTBMS) TRIFLUOROMETHANESULFONATE. PREPARATION AND SYNTHETIC APPLICATIONS OF DTBMS ESTERS AND ENOL ETHERS

DOI: 10.1016/S0040-4039(00)84069-1

Source and publish data:

Tetrahedron Letters p. 671 - 674 (1986)

Update date:2022-09-26

Topics:

Authors:

Bhide, Rajeev S.

Levison, Bruce S.

Sharma, Ram B.

Ghosh, Subrata

Salomon, Robert G.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)84069-1

DTBMS triflate, readily available from dichloromethylsilane, provides carboxylic esters which resist reduction by hydridoaluminate or acid catalyzed hydrolysis, and vinylogous esters ( enol ethers of hydroxymethylene ketones ) which resist 1,4-addition of methyllithium.

Full text of DOI:10.1016/S0040-4039(00)84069-1

Products guided by the article

Product name:(3aS,4aR,8aR,9aR)-6-[1-(Di-tert-butyl-methyl-silanyloxy)-meth-(E)-ylidene]-2,2,4a,5,9,9-hexamethyl-decahydro-naphtho[2,3-d][1,3]dioxol-5-ol

Cas No:105866-94-2

R&D Labs maybe for 105866-94-2

NanJing KaiHeng Chemical CO., LTD.

Contact:+86-25-85768391

Address:RM.1704, D, WANDA PLAZA, NO.110, MIDDLE JIANGDONG ROAD, NANJING, CHINA
ShiJiaZhuang Dowell Chemical Co.,Ltd.

website:http://www.dowechem.com

Contact:+86-13463963265

Address:Xiyangling village, high tech Zone, Shijiazhuang，Hebei, China
Yixing Bluwat Chemicals Co., Ltd.

Contact:+86 510 87821568

Address:Yongan Road, Yixing Chemical Industrial Park, Yixing, Jiangsu, China
KangZhiYuan Pharmaceutical Company Limited

Contact:(Sabrina)86-20-85273232

Address:4th floor, building B, Dadi industry zone, Tangxia, Tianhe, Guangzhou, China
Shanghai FWD Chemicals ltd

website:http://www.fwdchem.com

Contact:86-21-54450828

Address:Room 802,Lotus Tower ,159 Tianzhou Road,Xuhui District,Shanghai

Relevant to this article

ON THE REACTION OF N-VINYLIMINOPHOSPHORANES. A NOVEL ROUTE TO 1-AZAAZULENE RING SYSTEM UTILIZING AZA-WITTIG REACTION

Doi:10.1246/cl.1986.463
(1986)
An efficient and general method for the deoxygenation of organic N-oxides using Zn(OTf)₂ and Cu(OTf)₂

Doi:10.1055/s-2006-926269
(2006)
Regio- and stereochemistry of [2 + 2] photocycloadditions of imines to alkenes: A computational and experimental study

Doi:10.1021/jo8015242
(2008)
Immobilization of oligostyrene-prolinol conjugates into polystyrene via electrospinning and applications of these fibers in catalysis

Doi:10.1055/s-2008-1067146
(2008)
Doi:10.1021/ja01152a116
(1951)
Novel N₁-substituted 1,3-dihydro-2H-benzimidazol-2-ones as potent non-nucleoside reverse transcriptase inhibitors

Doi:10.1016/j.bmc.2008.06.012
(2008)

Article Doi