DI-TERT-BUTYLMETHYLSILYL (DTBMS) TRIFLUOROMETHANESULFONATE. PREPARATION AND SYNTHETIC APPLICATIONS OF DTBMS ESTERS AND ENOL ETHERS

DOI: 10.1016/S0040-4039(00)84069-1

Source and publish data:

Tetrahedron Letters p. 671 - 674 (1986)

Update date:2022-09-26

Topics:

Authors:

Bhide, Rajeev S.

Levison, Bruce S.

Sharma, Ram B.

Ghosh, Subrata

Salomon, Robert G.

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Article abstract of DOI:10.1016/S0040-4039(00)84069-1

DTBMS triflate, readily available from dichloromethylsilane, provides carboxylic esters which resist reduction by hydridoaluminate or acid catalyzed hydrolysis, and vinylogous esters ( enol ethers of hydroxymethylene ketones ) which resist 1,4-addition of methyllithium.

Full text of DOI:10.1016/S0040-4039(00)84069-1

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