DI-TERT-BUTYLMETHYLSILYL (DTBMS) TRIFLUOROMETHANESULFONATE. PREPARATION AND SYNTHETIC APPLICATIONS OF DTBMS ESTERS AND ENOL ETHERS

DOI: 10.1016/S0040-4039(00)84069-1

Source and publish data:

Tetrahedron Letters p. 671 - 674 (1986)

Update date:2022-09-26

Topics:

Authors:

Bhide, Rajeev S.

Levison, Bruce S.

Sharma, Ram B.

Ghosh, Subrata

Salomon, Robert G.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)84069-1

DTBMS triflate, readily available from dichloromethylsilane, provides carboxylic esters which resist reduction by hydridoaluminate or acid catalyzed hydrolysis, and vinylogous esters ( enol ethers of hydroxymethylene ketones ) which resist 1,4-addition of methyllithium.

Full text of DOI:10.1016/S0040-4039(00)84069-1

Products guided by the article

Product name:(3aS,4aR,8aR,9aR)-6-[1-(Di-tert-butyl-methyl-silanyloxy)-meth-(E)-ylidene]-2,2,4a,5,9,9-hexamethyl-decahydro-naphtho[2,3-d][1,3]dioxol-5-ol

Cas No:105866-94-2

R&D Labs maybe for 105866-94-2

Beijing Mediking Biopharm Co., Ltd.

Contact:+86-10-89753524/81760121/81769521

Address:Hongxianghong Incubator, Beiqijia Town, Changping district, Beijing, China
Hisyntech Corporation Limited

Contact:0086-22-23410962

Address:17-201, Ningfuli, Shuishanggongyuandong road,Nankai district, Tianjin, China
Sichuan Highlight Fine Chemicals Co., Ltd.

Contact:+86-28-8525 1605

Address:A5-102 Airport base,388 West Airport Huang He Zhong Lu,2 Section
Zibo Linzi Darong Fine Chemical Co., Ltd(expird)

Contact:86-532-67773200; 15689126900

Address:Qidu town,Linzi district,Zibo city,Shandong province,China
Wuhan Soleado Technology Co.,Ltd.

Contact:86-2783341481 18971291927

Address:RM2405 Unit 1 Builing 1, Taiyin Tower, Changqing Road,Wuhan China

Relevant to this article

ON THE REACTION OF N-VINYLIMINOPHOSPHORANES. A NOVEL ROUTE TO 1-AZAAZULENE RING SYSTEM UTILIZING AZA-WITTIG REACTION

Doi:10.1246/cl.1986.463
(1986)
An efficient and general method for the deoxygenation of organic N-oxides using Zn(OTf)₂ and Cu(OTf)₂

Doi:10.1055/s-2006-926269
(2006)
Regio- and stereochemistry of [2 + 2] photocycloadditions of imines to alkenes: A computational and experimental study

Doi:10.1021/jo8015242
(2008)
Immobilization of oligostyrene-prolinol conjugates into polystyrene via electrospinning and applications of these fibers in catalysis

Doi:10.1055/s-2008-1067146
(2008)
Doi:10.1021/ja01152a116
(1951)
Novel N₁-substituted 1,3-dihydro-2H-benzimidazol-2-ones as potent non-nucleoside reverse transcriptase inhibitors

Doi:10.1016/j.bmc.2008.06.012
(2008)

Article Doi