Inorganic Chemistry p. 1107 - 1110 (1963)
Update date:2022-09-26
Topics:
Alexander, Roy P.
Schroeder, Hansjuergen
Dilithiocarborane, B10H10C2Li2, was allowed to react with chlorophosphines containing one, two, and three chlorine atoms. (C6H5)2PCl and C6H5PCl2 gave the expected disubstituted compounds, B10H10C2[P(C6H5) 2]2 and B10H10C2(C6H 5P·Cl)2, respectively. B10H10C2Li2 and PCl3, however, formed a compound having two phosphorus atoms and two carborane nuclei in a six-membered ring. This unique ring system also arose from the reaction of B10H10C2Li2 with B10H10C2(C6H 5P·Cl)2. Subsequent reactions of such molecules with ammonia and NaN3 are described. The cyclic bis-azide, (B10H10C2P·N3)2. and p-[(C6H5)2P]2C6H 4 reacted to form a PNP bonded oligomer.
Hangzhou jls Flame Retardants Chemical Co.,Ltd
Contact:+86-571-87250387/87250386
Address:MOGANSHAN RODA 1418# SHANGCHENG INDUSTRIAL PARK
SHIFANG SUHONG CHEMICAL CO.,LTD
Contact:+86-838-2224563
Address:Room 1207 Zongchen Sunshine No.128 Taishan South Road,Deyang City,Sichuan China
Nanjing Qirui Material Co., Ltd.
Contact:+86-25-52320053
Address:F4-5, #17 Building, Chuang Yi Yuan, No.6 Guanghua East Street, Nanjing, 210007 P.R.China
Jinan Hongfangde Pharmatech Co.LTD
Contact:0531-88870908
Address:F Bldg,750#,Shunhua Rd,New&High-tech Zone,Jinan,Shandong,China 250101
Nanjing Ruizhi Industry & Technologh Co.，Ltd.
Contact:+86-25-86808110
Address:441-4-A5,NO.12 Longzang Avenue,Yuhuatai District,210039,Nanjing
Doi:10.1007/bf00806859
(1997)Doi:10.1021/jo100563p
(2010)Doi:10.1016/S0040-4020(97)00841-7
(1997)Doi:10.1016/S0040-4039(97)01630-4
(1997)Doi:10.1021/jo9714829
(1997)Doi:10.1055/s-1996-4328
(1996)
