TRANSANNULAR RING EXPANSION OF THE SPIROCYCLOPROPANE MOIETY IN THE ACID CATALYZED REARRANGEMENT OF OXIRANES DERIVED FROM NORBORNENE AND BICYCLOOCTENE.

DOI: 10.1016/S0040-4039(00)84796-6

Source and publish data:

Tetrahedron Letters p. 3361 - 3364 (1986)

Update date:2022-09-26

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Authors:

Adam, Waldemar

Cramer, Elisabeth

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Article abstract of DOI:10.1016/S0040-4039(00)84796-6

Treatment of the spirocyclopropane derivatives of epoxy norbornane 5 and epoxy bicyclo<2.2.2>octane 6 with trifluoroacetic acid and perchloric acid affords the substituted brendanes 7 and 9 and homobrendanes 8 and 10 respectively.

Full text of DOI:10.1016/S0040-4039(00)84796-6

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