Tetrahedron p. 3981 - 3986 (1986)
Update date:2022-07-29
Topics:
Malmberg, Hans
Nilsson, Martin
2-Arylpyridines are formed rather selectively in 50 to 80 percent yields from 2-pyridylcopper and unactivated iodoarenes in the presence of one to two mol triphenylphosphine in toluene around 100 deg C.The selectivity may be due to the ability of the copper(I) iodide-triphenylphosphine complex as a leaving group or may be discussed in terms of oxidative addition/reductive elimination.The unsymmetric coupling reaction may be general since the coupling of phenylcopper/triphenylphosphine with 2-iodopyridine also gives 2-phenylpyridine.
View MoreNanjing Capatue Chemical Co., Ltd
Contact:+86-25-86371192 +86-025-85720158
Address:No.20 Jiangjun Avenue, Jiangning Economic & Technical Development Zone
Contact:86+21-56421993
Address:3F,BUILDING 10,NO.2889 JINKE ROAD, SHANGHAI.
KangZhiYuan Pharmaceutical Company Limited
Contact:(Sabrina)86-20-85273232
Address:4th floor, building B, Dadi industry zone, Tangxia, Tianhe, Guangzhou, China
Contact:86-21-50966856
Address:Building 5,300 Chuanzhan Road,Pudong New District,Shanghai
Global United Biotechnology Inc.
Contact:+86-21-61618568
Address:Room 309, Building 6, NO.135, Jinyu Road, Pudong
Doi:10.1021/jo00387a002
(1987)Doi:10.1016/0022-328X(88)80652-1
(1988)Doi:10.1002/hlca.19620450608
(1962)Doi:10.1002/ejoc.200800472
(2008)Doi:10.1016/j.tet.2008.07.088
(2008)Doi:10.1002/jhet.5570230314
(1986)
