Journal of Organic Chemistry p. 12588 - 12593 (2015)
Update date:2022-09-26
Topics:
Dong, Jiawei
Wu, Zhongjie
Liu, Zhengyi
Liu, Ping
Sun, Peipei
2-(Alkylamino)benzonitriles were synthesized via a rhodium-catalyzed cyanation on the aryl C-H bond and subsequent denitrosation of N-nitrosoarylamines using a removable nitroso as the directing group, in which N-cyano-N-phenyl-p-methylbenzenesulfonamide (NCTS) was used as the "CN" source. Various substituents on the aryl ring and amino group of N-nitrosoarylamines tolerated the reaction, and the corresponding products were achieved in moderate to good yields.
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