Intramolecular -Cycloadditions of Vinylnitrosonium Cations with Olefins

DOI: 10.1021/jo00381a028

Source and publish data:

Journal of Organic Chemistry p. 877 - 887 (1987)

Update date:2022-08-05

Topics:

Authors:

Denmark, Scott E.

Cramer, Christopher J.

Dappen, Michael S.

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Article abstract of DOI:10.1021/jo00381a028

α,β-Epoxyketonitrones have been shown to be viable precursors of vinylnitrosonium cations upon treatment with trimethylsilyl trifluoromethanesulfonate.Variable-temperature NMR experiments indicate that this transformation occurs slowly at room temperature

Full text of DOI:10.1021/jo00381a028

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