OPTICALLY ACTIVE NITROGEN LIGAND. III. ENANTIOFACE-DISCRIMINATING TRANSFER HYDROGENATION OF ACETOPHENONE CATALYZED BY RHODIUM(I) COMPLEXES WITH CHIRAL 2-(2'-PYRIDYL)PYRIDINES

DOI: 10.1016/S0022-328X(00)99687-6

Source and publish data:

Journal of Organometallic Chemistry p. 217 - 226 (1986)

Update date:2022-08-05

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Authors:

Botteghi, C.

Chelucci, G.

Chessa, G.

Delogu, G.

Gladiali. S.

Soccolini, F.

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Article abstract of DOI:10.1016/S0022-328X(00)99687-6

The reduction of acetophenone by hydrogen transfer from isopropanol is catalyzed by rhodium(I) complexes containing optically active 2-(2'-pyridyl)pyridines.Optical yields up to 15percent have been obtained.

Full text of DOI:10.1016/S0022-328X(00)99687-6

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