GENERATION AND CYCLIZATION OF NITRILIUM IONS FROM AMIDES. ASYMMETRIC SYNTHESIS OF FUSED AZABICYCLICS

DOI: 10.1016/S0040-4039(00)84451-2

Source and publish data:

Tetrahedron Letters p. 2071 - 2074 (1986)

Update date:2022-07-29

Topics:

Authors:

Gawley, Robert E.

Chemburkar, Sanjay

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)84451-2

Treatment of 2^o amides with PPSE affords nitrilium ions which may be cyclized onto appropriate terminators.The conditions are compatible with esters in the molecule, and further elaboration to pyrrolizidine and indolizidine rings is possible vi

Full text of DOI:10.1016/S0040-4039(00)84451-2

Products guided by the article

Product name:(S)-2-Methyl-3-[1-phenyl-meth-(E)-ylidene]-pyrrolidine

Cas No:106814-14-6

R&D Labs maybe for 106814-14-6

Heliosense Biotechnologies, Inc.

Contact:+86-592-5667290

Address:Xiamen Torch Hi-tech Zone Venture Weiye Building S506
Zhenjiang Haitong Chemical Industry Co., Ltd.

Contact:+86 (511) 8448-0369

Address:Baoyan Town, Dantu District, Zhenjiang City, Jiangsu, China
HANGZHOU YUNUO CHEMICAL CO.,LTD

website:http://www.yunuochem.com

Contact:0571-83715115

Address:hangzhou
Sarchem Laboratories, Inc.

Contact:732.938.2777

Address:5012 Industrial Road Farmingdale, NJ 07727
Changzhou Hopschain Chemical Co.,Ltd

website:http://www.hopschem.cn/products.html

Contact:86-519-85528066

Address:Room 710, Unit A, Xingbei Development Mansion, Tongjiang Road, Changzhou City,213000, China

Relevant to this article

Doi:10.1007/BF00759528
()
A new five-membered ring forming process based on palladium(0)-catalyzed arylative cyclization of allenyl enones

Doi:10.1021/ol800509z
(2008)
Macrocyclic 14-membered ring diketal diamines: Synthesis, conformational analysis and ^99mTc radiolabeling evaluation

Doi:10.1002/ejoc.200701151
(2008)
Doi:10.1021/ja01510a026
(1959)
Self-assembled dendrimers with uniform structure

Doi:10.1039/b803519a
(2008)
Enantioselective Reduction of Vicinally Substituted Monocyclic Aldehydes with Horse Liver Alcohol Dehydrogenase; A New Approach to Chiral Alcohols and Aldehydes

Doi:10.1055/s-1987-27830
(1987)

Article Doi