Journal of the Chemical Society, Dalton Transactions p. 2381 - 2386 (1986)
Update date:2022-08-04
Topics:
Woon, Tai Chin
McDonald, Robert
Mandal, Sanat K.
Thompson, Laurence K.
Connors, Sean P.
Addison, Anthony W.
Binuclear, hydroxo-bridged, copper(II) complexes of a series of quadridentate pyridazine and phthalazine thioether ligands involving nitrogen donor groups (derived from pyridine, imidazole, benzimidazole) exhibit room-temperature magnetic moments in the range 1.1-1.7 B.M., indicative of antiferromagnetically coupled binuclear copper(II) centres.Cyclic voltammetry and coulometry on most of these systems indicate reversible or quasi-reversible redox processes, involving two-electron transfer, at positive potentials (0.23-0.49 V vs. a saturated calomel electrode in CH3CN or dimethylformamide).Mononuclear copper(II) derivatives, involving bidentate ligands, also exhibit reduction at positive potentials.Catecholase activity involving 3,5-di-t-butylbenzene-1,2-diol has been demonstrated for the hydroxo-bridged complex
Taizhou Crene Biotechnology co.ltd
Contact:86-576-88813233 88205808
Address:Economic Developed Zone of Taizhou Zhejiang China
Guangxi Shanyun Biochemical Science and Technology Co., Ltd
Contact:+86-0772--6828887
Address:#2 Industrial Park of Luzhai County, Liuzhou, Guangxi, China
Frapp's Chemical (NFTZ) Co.,Ltd
Contact:+86-576-86137892
Address:General Chamber of Commercial Building, 159 Wanchang Middle Road, Wenling, Zhejiang, China
Shanghai Sunway Pharmaceutical Technology Co.,Ltd.
Contact:+86-21-5161 3915
Address:Shanghai YangPu
Guangzhou Reachin Chemical Co., Ltd
Contact:+86-20-37087379 ext.604
Address:A122C-1, Tianyuan Plaza, 401 Tianyuan Rd., Tianhe, Guangzhou, China
Doi:10.1021/ol801797h
(2008)Doi:10.1021/jo00382a024
(1987)Doi:10.1002/ejoc.201300699
(2013)Doi:10.1002/anie.201905173
(2019)Doi:10.1039/c5dt00369e
(2015)Doi:10.1021/ja00235a031
(1987)
