Journal of the Chemical Society, Dalton Transactions p. 2381 - 2386 (1986)
Update date:2022-08-04
Topics:
Woon, Tai Chin
McDonald, Robert
Mandal, Sanat K.
Thompson, Laurence K.
Connors, Sean P.
Addison, Anthony W.
Binuclear, hydroxo-bridged, copper(II) complexes of a series of quadridentate pyridazine and phthalazine thioether ligands involving nitrogen donor groups (derived from pyridine, imidazole, benzimidazole) exhibit room-temperature magnetic moments in the range 1.1-1.7 B.M., indicative of antiferromagnetically coupled binuclear copper(II) centres.Cyclic voltammetry and coulometry on most of these systems indicate reversible or quasi-reversible redox processes, involving two-electron transfer, at positive potentials (0.23-0.49 V vs. a saturated calomel electrode in CH3CN or dimethylformamide).Mononuclear copper(II) derivatives, involving bidentate ligands, also exhibit reduction at positive potentials.Catecholase activity involving 3,5-di-t-butylbenzene-1,2-diol has been demonstrated for the hydroxo-bridged complex
LianYunGang Chiral Chemical(CHINA) CO.,LTD
Contact:+86-518-83616958 +86-519-82884848
Address:LianYunGang Chemical Industry Park (JiangSu)
website:http://www.weichichem.com
Contact:+8613912949432
Address:Fine Chemical Industrial Base,Wujiang town,He County,Anhui China.
NINGBO PANGS CHEM INT’L CO., LTD.
Contact:+86-0574-27666801
Address:Floor 21, Building 11, Xintiandi, No. 689, Shijiroad, Ningbo, Zhejiang, China
Binzhou Holly Pharmaceutical Co.,Ltd.
Contact:74517
Address:No.15 Dapu Road,Huangpu District Shanghai,P.R.China
Chengdu Yunyi International Trade Co., Ltd
Contact:
Address:china
Doi:10.1021/ol801797h
(2008)Doi:10.1021/jo00382a024
(1987)Doi:10.1002/ejoc.201300699
(2013)Doi:10.1002/anie.201905173
(2019)Doi:10.1039/c5dt00369e
(2015)Doi:10.1021/ja00235a031
(1987)
