ASYMMETRIC DIELS-ALDER CYCLOADDITIONS USING CHIRAL ALKYL VINYL ETHERS AND A DIENYL SULFONE

DOI: 10.1016/S0040-4039(00)84068-X

Source and publish data:

Tetrahedron Letters p. 667 - 670 (1986)

Update date:2022-08-03

Topics:

Authors:

Posner, Gary H.

Wettlaufer, David G.

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Article abstract of DOI:10.1016/S0040-4039(00)84068-X

Chiral alkyl vinyl ethers 2b-2j underwent mild, inverse electron demand, Diels-Alder cycloadditions with 3-arenesulfonyl-2-pyrone 1 to form bridged bicyclic lactone adducts 3b-3j in excellent yields and with diastereoselectivities of up to 90percent.

Full text of DOI:10.1016/S0040-4039(00)84068-X

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