Monatshefte fur Chemie p. 883 - 886 (1986)
Update date:2022-08-02
Topics:
Scharf, Josef
Schloegl, Karl
Weissensteiner, Walter
Complexation of bis(2,4-dimethyl-6-tert.butyl-phenyl)ketone with chromium hexacarbonyl yields a mixture of two diastereomeric mono complexes in a ratio of 5:1.They can be separated by chromatography on silica gel at room temperature thus representing stable torsional isomers (isolable residual diastereomers). - Keywords: Residual diastereomers; Torsional barrier; Complexation with hexacarbonylchromium
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