Journal of the Chemical Society. Chemical communications p. 1170 - 1171 (1986)
Update date:2022-09-26
Topics:
Kerschl, Susanna
Wrackmeyer, Bernd
The reaction of the system (E)-2-dimethyl(chloro)stannyl-3-diethylborylpent-2-ene (1)-LiNEt2 in hexane can be controlled to give 1,4-dihydro-1,1,2,4,4,5-hexamethyl-3,6-diethyl-1,4-distannine (3) in high yield, demonstrating the imtermediacy of aminoborate (5) and the preference (under the reaction conditions) of intermolecular electrophilic attack at the B-C= bond accompanied by final elimination of LiCl and Et2NBEt2 (4).
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Doi:10.1039/jr9550000423
(1955)Doi:10.1246/bcsj.59.1629
(1986)Doi:10.1016/j.tetlet.2008.07.180
(2008)Doi:10.1055/s-2008-1078496
(2008)Doi:10.1021/jm00388a016
(1987)Doi:10.1016/S0040-4039(00)84677-8
(1986)
