1H NMR 2D Conformational Study of 2-Selenated 3-Substituted Cyclohexanones. Evidence of Trans Diaxial Conformers

DOI: 10.1021/jo00358a024

Source and publish data:

Journal of Organic Chemistry p. 1293 - 1298 (1986)

Update date:2022-09-26

Topics:

Authors:

Zervos, Michel

Wartski, Lya

Goasdoue, Nicole

Platzer, Nicole

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00358a024

Syntheses of various cis and trans 2-phenylseleno 3-substituted cyclohexanones (1-4) are described as well as related ketals (5-6).The 1H NMR 2D study shows that the 2-SePh group is located in axial position in both cis (1-4c) and trans (1, 2, and 4t) ket

Full text of DOI:10.1021/jo00358a024

Products guided by the article

Product name:trans-2-(phenylseleno)-3-cyclohexanone

Cas No:107078-92-2

R&D Labs maybe for 107078-92-2

Zhonghao (dalian) Research and Design Institute of Chemical Industry Co., Ltd

Contact:+86 411 84674606

Address:201, Huangpu Road , Shahekou District, Dalian ,116023-China
Hangzhou Bayee Chemical Co.,Ltd.

Contact:+86-571-86990109

Address:No.380, Jiangnan Auenue, Binjiang District, Hangzhou, China
CHINA MEHECO CORPORATION

Contact:+86-10-67147360/67107388

Address:No.18 Guangming Zhongjie, Chongwen District, Beijing, 100061, China
Shanghai Pengkai Chemical Co.,Ltd

Contact:+86-21-60526671

Address:No.4226 Duzhuang Rd Minhang District Shanghai China
Shanghai Yuking Water Soluble Material Tech Co., Ltd

Contact:86-21-68286299

Address:4F, 13B, No. 600, South Xinyuan Road 201306, Shanghai, China

Relevant to this article

Synthesis of some 2,2′:6′,2″-terpyridines disubstituted in positions 6 and 6″ with head-to-tail oriented amino acids and dipeptides: A simple entry to a reversible inducer of folding in amino acid sequences

Doi:10.1002/ejoc.200800433
(2008)
A new and efficient one-pot synthesis of 2-hydroxy-1,4-dihydrobenzoxazines via a three-component Petasis reaction

Doi:10.1016/j.tetlet.2014.07.093
(2014)
Multistep Reversible Redox Systems. 48. 1,3-Bisquinone Methide Cyclobutanes and Related Bicyclo<1.1.0>butanes: Syntheses and Redox Properties

Doi:10.1021/jo00387a007
(1987)
Chromium(III) complexes bearing 2-imino-1,10-phenanthrolines: Synthesis, molecular structures and ethylene oligomerization and polymerization

Doi:10.1016/j.molcata.2007.07.012
(2007)
Doi:10.1139/v60-262
(1960)
Antimycobacterial eudesmanolides from Inula helenium and Rudbeckia subtomentosa

Doi:10.1055/s-1999-14001
(1999)

Article Doi