SYNTHESIS OF 4-( CYANOMETHYLIDENE)- AND 4-( ETHOXYCARBONYLMETHYLIDENE)-4,5,6,7-TETRAHYDROINDOLES AND THEIR DEHYDROGENATION TO 4-( CYANOMETHYL)- AND 4-( ETHOXYCARBONYLMETHYL)INDOLES

DOI: 10.3987/R-1986-09-2611

Source and publish data:

Heterocycles p. 2611 - 2618 (1986)

Update date:2022-08-04

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Authors:

Matsumoto, Masakatsu

Watanabe, Nobuko

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Article abstract of DOI:10.3987/R-1986-09-2611

The Horner-Wittig reaction of 4-oxo-4,5,6,7-tetrahydroindoles with (EtO)2P(O)CH2CN and (EtO)2P(O)CH2CO2Et yielded respectively 4-(cyanomethylidene)- and 4-(ethoxycarbonylmethylidene)-4,5,6,7-tetrahydroindoles, which were catalytically dehydrogenated to 4-

Full text of DOI:10.3987/R-1986-09-2611

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Product name:[1-(Toluene-4-sulfonyl)-1,5,6,7-tetrahydro-indol-(4Z)-ylidene]-acetonitrile

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