Charge Reversal of Electrophilic ?-Allylpalladium Intermediates: Carbonyl Allylation bu Allylic Acetates with Pd(PPh3)4-Zn

DOI: 10.1021/jo00392a044

Source and publish data:

Journal of Organic Chemistry p. 3702 - 3704 (1987)

Update date:2022-09-26

Topics: Allylic Acetates

Authors:

Masuyama, Yoshiro

Kinugawa, Nobuyoshi

Kurusu, Yasuhiko

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Article abstract of DOI:10.1021/jo00392a044

Allylic acetates were reduced by zinc in the presence of a catalytic amount of Pd(PPh3)4 to serve as nucleophilic allylating agents, which reacted with aldehydes to afford the corresponding homoallylic alcohols.

Full text of DOI:10.1021/jo00392a044

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