Journal of the Chemical Society. Perkin transactions I p. 829 - 836 (1986)
Update date:2022-08-02
Topics:
Shishido, Kozo
Hiroya, Kou
Ueno, Yutaka
Fukumoto, Keiichiro
Kametani, Tetsuji
Honda, Toshio
An efficient and highly stereoselective synthesis of functionalized tricyclo<6.3.1.01.6>dodec-4-enes (1c,e,f-h), which would be useful and common synthons for constructing basic carbon frameworks of various kinds of natural products, is described.The key feature of the synthesis was a stereoselective intramolecular Diels-Alder reaction of the cyclohexanone derivatives (10c,e,f-h), which were easly derived from cyclohexanone in 4-5 steps.The whole structure and the stereochemistry of a major cycloadduct (1e) was established by a single-crystal X-ray analysis.
View Morewebsite:http://www.cartoonchem.com/
Contact:+86-25-58074918
Address:Room 2109, RuiHua Business Center,315 South ZhongShan Road, Nanjing 210001, China
Yixing Zhenfen Medical Chemical Co.Ltd
Contact:86-510-87552708
Address:Fenshui ,Yixing city,Jiangsu
Tianjin Ingenochem Technology Co.,Ltd
Contact:+86-22-23677060
Address:Hitech Green Industry Park K2-9-602, Nankai district
Suzhou Credit International Trading Co., Ltd
Contact:+86-512-65398039
Address:Qingdeng, Hightech. District, Suzhou
shijiazhuang shuanglian chemical industry co.,ltd
Contact:0311-82190302
Address:Luquan Intersection , Shijiazhuang--Taiyuan Expressway，Shijiazhuang City
Doi:10.1021/acs.joc.7b02674
(2018)Doi:10.1039/b925644j
(2010)Doi:10.1002/chem.200902774
(2010)Doi:10.1016/j.tet.2010.01.024
(2010)Doi:10.1007/BF00474046
(1988)Doi:10.1016/j.ica.2009.11.023
(2010)
