Organometallics p. 982 - 987 (1987)
Update date:2022-07-29
Topics:
Burch, Robert R.
Harlow, Richard L.
Ittel, Steven D.
The fluoro-bridged cluster [FRh(C2H4)(C2F4)]4 was prepared by treatment of [ClRh(C2H4)(C2F4)]2 with AgBF4, followed by reaction with [(CH3)2N]3S+(CH3) 3SiF2-. The cubanelike structure of the tetrameric complex was established by X-ray crystallography. Reaction of [FRh(C2H4)(C2F4)]4 with P(C6H5)3 yielded the new monometallic complex FRh(C2F4)[P(C6H5)3] 2. The monometallic rhodium-fluoride complex can undergo reactions involving ligand substitution or fluoride extraction. In a ligand substitution reaction, solutions of FRh(C2F4)[P(C6H5)3] 2 react with CO to give FRh(CO) [P(C6H5)3]2. Reaction with (CH3)3SiO3SCF3 yielded CF3SO3Rh(C2F4)[P(C6H 5)3]2, derived from the fluoride extraction reaction.
TIANJIN FESTO CHEMICAL CO.,LTD(expird)
Contact:86-22-25814570
Address:No.12th,5th Ave.,TEDA,Tianjin,China
Tangshan Moneide Trading Co., Ltd.
Contact:+86-315-8309571
Address:2-7-420 Jidong Building Materials Commercial Center, Tangshan, Hebei, 064000 China
Synochem Ingredients Corp., Ltd.
Contact:+86-512-5636 2180
Address:Zhangjiagang Free Trade Zone
Anhui Asahikasei Chemical Co., Ltd
Contact:86-551-4259770
Address:No. 88 Linquan Road Hefei Anhui China
Tianjin Chemsyntech Chemical Co., Ltd
Contact:+86-22-60872258
Address:Haitai green industry base in Tianjin, K1,5-601
Doi:10.1016/S0040-4039(00)84602-X
(1986)Doi:10.1021/jm00388a039
(1987)Doi:10.1021/om00105a034
(1989)Doi:10.1007/BF00763715
(1986)Doi:10.1002/jhet.5570450515
(2008)Doi:10.1002/hlca.19950780113
(1995)
