Organometallics p. 982 - 987 (1987)
Update date:2022-07-29
Topics:
Burch, Robert R.
Harlow, Richard L.
Ittel, Steven D.
The fluoro-bridged cluster [FRh(C2H4)(C2F4)]4 was prepared by treatment of [ClRh(C2H4)(C2F4)]2 with AgBF4, followed by reaction with [(CH3)2N]3S+(CH3) 3SiF2-. The cubanelike structure of the tetrameric complex was established by X-ray crystallography. Reaction of [FRh(C2H4)(C2F4)]4 with P(C6H5)3 yielded the new monometallic complex FRh(C2F4)[P(C6H5)3] 2. The monometallic rhodium-fluoride complex can undergo reactions involving ligand substitution or fluoride extraction. In a ligand substitution reaction, solutions of FRh(C2F4)[P(C6H5)3] 2 react with CO to give FRh(CO) [P(C6H5)3]2. Reaction with (CH3)3SiO3SCF3 yielded CF3SO3Rh(C2F4)[P(C6H 5)3]2, derived from the fluoride extraction reaction.
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Doi:10.1016/S0040-4039(00)84602-X
(1986)Doi:10.1021/jm00388a039
(1987)Doi:10.1021/om00105a034
(1989)Doi:10.1007/BF00763715
(1986)Doi:10.1002/jhet.5570450515
(2008)Doi:10.1002/hlca.19950780113
(1995)
