Organometallics p. 982 - 987 (1987)
Update date:2022-07-29
Topics:
Burch, Robert R.
Harlow, Richard L.
Ittel, Steven D.
The fluoro-bridged cluster [FRh(C2H4)(C2F4)]4 was prepared by treatment of [ClRh(C2H4)(C2F4)]2 with AgBF4, followed by reaction with [(CH3)2N]3S+(CH3) 3SiF2-. The cubanelike structure of the tetrameric complex was established by X-ray crystallography. Reaction of [FRh(C2H4)(C2F4)]4 with P(C6H5)3 yielded the new monometallic complex FRh(C2F4)[P(C6H5)3] 2. The monometallic rhodium-fluoride complex can undergo reactions involving ligand substitution or fluoride extraction. In a ligand substitution reaction, solutions of FRh(C2F4)[P(C6H5)3] 2 react with CO to give FRh(CO) [P(C6H5)3]2. Reaction with (CH3)3SiO3SCF3 yielded CF3SO3Rh(C2F4)[P(C6H 5)3]2, derived from the fluoride extraction reaction.
HANGZHOU FOREWIN PHARMA CO., LTD
Contact:+86-571-89053961
Address:hangzhou
Beijing Apis Biotechnology Co., Ltd.
Contact:86-010-67856775-8551
Address:NO.4PUHUANGYU ROAD,FENTAI DISTRICT, BEIJING, CHINA
Jinan Jianfeng Chemical Co., Ltd
Contact:0086-531-88110457
Address:sales01(-a-t-)pharmachemm{dot}c+o+m
Contact:86-21-58226973
Address:No 351,Guoshoujing Road, Zhangjiang Hi-tech Park, Pudong, Shanghai, China
Angelisun(Chongqing) Pharmaceutical Co., LTD.
Contact:+86-23-68030926-816
Address:D1-7 Tech & Entrepreneurs Park, Kecheng Road, Erlang Hi-Tech Areas, Chongqing, China
Doi:10.1016/S0040-4039(00)84602-X
(1986)Doi:10.1021/jm00388a039
(1987)Doi:10.1021/om00105a034
(1989)Doi:10.1007/BF00763715
(1986)Doi:10.1002/jhet.5570450515
(2008)Doi:10.1002/hlca.19950780113
(1995)
