Preparation of Titanium Pentamethylcyclopentadienyl Trialkyls and Crystal Structure of Tribenzylpentamethylcyclopentadienyltitanium, showing Some Evidence of a CH2...Ti Interaction

DOI: 10.1039/c39860001118

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1118 - 1119 (1986)

Update date:2022-08-03

Topics:

Authors:

Mena, Miguel

Pellinghelli, Maria Angela

Royo, Pascual

Serrano, Ricardo

Tripicchio, Antonio

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39860001118

Titanium pentamethylcyclopentadienyl trialkyls (η⁵-C5Me5)TiR3 (R = Me, CH2SiMe3, C6F5, and CH2Ph) are easily obtained by conventional alkylation of the trichloro analogue; the structure of the tribenzyl derivative, determined by X-ray methods, shows some evidence of CH2...Ti interaction.

Full text of DOI:10.1039/c39860001118

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(pentamethylcyclopentadienyl)titanium tribenzyl

Cas No:107333-50-6

R&D Labs maybe for 107333-50-6

Shanghai Longschem Co.,Ltd

Contact:021-36356756

Address:Room601,Building No.14,280 Yangcheng Road,Shanghai
Zhengzhou Minzhong Pharmaceutical Co.,ltd

Contact:0086-371-65797115

Address:15/F,Jiangshan Bldg, NO.126 Huanghe Road,Zhengzhou, China
Liaoyang hengye Chemical Co., Ltd.

Contact:86-419-5850866

Address:North Old Xiaoxiao Road,Yantai District, Dengta, Liaoyang, Liaoning, China
Hawks Chemical

Contact:+44 (0)161 367 9441

Address:
Hangzhou Gangjin Chemical Co.,Ltd.(expird)

Contact:+86-571-85109780

Address:707 Zhejiang Minhang Bldg., No.290 Zhongshan North Road, Hangzhou 310003, China

Relevant to this article

Doi:10.1007/BF00899843
(1960)
Iridium-catalyzed preparation of silylboranes by silane borylation and their use in the catalytic borylation of arenes

Doi:10.1021/om800696d
(2008)
Biological activities and quantitative structure-activity relationships of spiro[imidazolidine-4,4'(1'H)-quinazoline]-2,2',5(3'H)-triones as aldose reductase inhibitors

Doi:10.1021/jm00089a021
(1992)
A new entry to enantiopure polysubstituted cyclopropanes: Stereoselective denitrogenation of sulfinylpyrazolines under Yb(OTf)₃ catalysis

Doi:10.1021/ol061168d
(2006)
Isolation, chemical analysis, and study of the hepatoprotector and biligenic activity of total flavonoid preparations from Thermopsis dolichocarpa and Vexibia alopecuroides

Doi:10.1023/A:1010450709980
(2001)
Design and synthesis of cage-like NADH model molecule intermediate with multi-chiral centers

Doi:10.1080/00397911.2018.1557689
(2019)

Article Doi