Preparation of Titanium Pentamethylcyclopentadienyl Trialkyls and Crystal Structure of Tribenzylpentamethylcyclopentadienyltitanium, showing Some Evidence of a CH2...Ti Interaction

DOI: 10.1039/c39860001118

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1118 - 1119 (1986)

Update date:2022-08-03

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Authors:

Mena, Miguel

Pellinghelli, Maria Angela

Royo, Pascual

Serrano, Ricardo

Tripicchio, Antonio

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Article abstract of DOI:10.1039/c39860001118

Titanium pentamethylcyclopentadienyl trialkyls (η⁵-C5Me5)TiR3 (R = Me, CH2SiMe3, C6F5, and CH2Ph) are easily obtained by conventional alkylation of the trichloro analogue; the structure of the tribenzyl derivative, determined by X-ray methods, shows some evidence of CH2...Ti interaction.

Full text of DOI:10.1039/c39860001118

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