Reactions with Aziridines; 34. γ-Amidoketones by Amidoethylation of Ketones

DOI: 10.1055/s-1986-31648

Source and publish data:

Synthesis p. 392 - 395 (1986)

Update date:2022-07-29

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Authors:

Stamm, Helmut

Weiss, Rainer

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Article abstract of DOI:10.1055/s-1986-31648

Sodium enolates of ketones react with 1-acyl-, 1-aminocarbonyl, and 1-alkoxycarbonylaziridines to give γ-amidoketones .Twofold amidoethylation in α,α- or α,α'-position can usually be suppressed by using excess enolate, exept for the amidoethylation of 1-indanone.

Full text of DOI:10.1055/s-1986-31648

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