Tetrahedron Letters p. 2873 - 2876 (1984)
Update date:2022-09-26
Topics:
Bluthe, Norbert
Malacria, Max
Gore, Jacques
The entitled alcohols are smoothly converted to αδ-diethylenic ketones by treatment with one molar equivalent of silver trifluorosulfonate in THF-H2O at 20 to 60 deg C.The yield of the transposition is excellent but a loss of unstable ketones is observed during the purification.
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(1983)