Journal of Organometallic Chemistry p. 361 - 366 (1986)
Update date:2022-09-26
Topics:
Mlekuz, Michael
D'Agostino, Michael F.
Kolis, Joseph W.
McGlinchey, Michael J.
CpMoCo2(CO)8CCO2ChMe2 in propionic anhydride reacts with HPF6 to yield the mixed metal acylum cation CpMoCo2(CO)8CCO+ which reacts with a variety of nucleophiles, e.g.ROH, R2NH yielding cluster-bound esters and amides, respectively.The cation also reacts with PhNMe2 in a Friedel-Crafts process.In the presence of water, Co3(CO)9CCO+ can also decompose to yield the neutral dimer <(Co3(CO)9C>2.
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Doi:10.1016/S0040-4039(00)84729-2
(1986)Doi:10.2174/157017812802850276
(2012)Doi:10.1002/adsc.201600389
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(1973)Doi:10.1007/s11178-008-2010-y
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