REMOTE INTRAMOLECULAR FUNCTIONALIZATION OF ARYLNITRENIUM IONS: SYNTHESIS OF AMINO-DIHYDROPHENANTHRIDINES AND BENZOCHROMANS.

DOI: 10.1016/S0040-4039(00)83858-7

Source and publish data:

Tetrahedron Letters p. 3705 - 3708 (1986)

Update date:2022-08-03

Topics:

Authors:

Abramovitch, Rudolph A.

Cooper, Melanie M.

Jeyaraman, Ramasubbu

Rusek, Grzegorz

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)83858-7

4-Aminobenzochroman (6) and 3-amino-5-acetyl-5,6-dihydrophenanthridine (9) are synthesized by intramolecular trapping of the delocalized nitrenium ions from 3-azidobenzyl phenyl ether and 3-azido-N-benzylacetanilide, respectively.On the other hand, no cyclization product is obtained from 3-azidophenyl benzyl ether, possibly owing to an ortho-effect exerted by the oxygen atom ortho to the developing ?-aryl cation.

Full text of DOI:10.1016/S0040-4039(00)83858-7

Products guided by the article

Product name:3-azidobenzyl phenyl ether

Cas No:107826-10-8

R&D Labs maybe for 107826-10-8

Chemieliva Pharmaceutical Co., Ltd.

website:http://www.chemieliva.com

Contact:+86-23-67770219

Address:99 Longhua Road, Yubei District, 401147, Chongqing, China Email: sales@chemieliva.com Tel:0086-23-67770219 Fax: 0086-23-67770220 Attn: Andy Huang
SPE Chemicals Co.,Ltd

Contact:

Address:ROOM 1715, No#345 Jin Xiang Road, Pudong District
Debye Scientific

website:http://www.debyesci.com

Contact:+85221376140

Address:Rm. 19C, Lockhart Ctr., 301-307 Lockhart Rd., Wan Chai
Airsea(Taizhou) Pharmaceutical Limited(expird)

Contact:+86-576-88057622

Address:Dubei, Duqiao, Linhai, Taizhou, Zhejiang, China Zip: 317016
Sinopharma Yibin Pharmaceutical Co.,Ltd

Contact:86-831-5109854

Address:Luolong Industry Zone

Relevant to this article

Photoredox-Assisted Reductive Cross-Coupling: Mechanistic Insight into Catalytic Aryl-Alkyl Cross-Couplings

Doi:10.1021/acs.joc.6b02830
(2017)
Synthesis and antiproliferative activity of unnatural enantiomers of 7-epi-goniofufurone and crassalactone C

Doi:10.1016/j.bmcl.2008.08.093
(2008)
Simple synthesis of 3-hydroxyquinolines via Na₂S₂O₄-mediated reductive cyclization of (2-(2-nitrophenyl)oxiran-1-yl)(aryl)methanones (o-nitrobenzalacetophenone oxides)

Doi:10.1016/j.tet.2017.06.058
(2017)
Bioisosteric replacement of the pyrazole 3-carboxamide moiety of rimonabant. A novel series of oxadiazoles as CB1 cannabinoid receptor antagonists

Doi:10.1039/b807648k
(2008)
SYNTHESIS OF 2,5-SUBSTITUTED 1,3,4-THIADIAZOLES FROM 3-PHENYL-5-METHYL-4-ISOXAZOLYLHYDRAZIDE

Doi:10.1007/BF00765111
(1987)
Doi:10.1021/ja01527a035
(1959)

Article Doi