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Borane Anions with Bridging Cyanide Ligands; Preparation and Properties of Derivatives of - and -

DOI: 10.1039/DT9860002645

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2645 - 2650 (1986)

Update date:2022-08-05

Topics:

Authors:

Meina, Dominic G.Meina, Dominic G.

Morris, John H.Morris, John H.

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Article abstract of DOI:10.1039/DT9860002645

A series of cyanide-bridged derivatives of the arachno-octahydrotriborate(1-) and arachno-tetradecahydrononaborate(1-) ions, - and - respectively, have been prepared using chemical and electrochemical methods.Compounds prepared include the triborate species - and its substituted derivatives, - and -, together with the ions - and -.The ions - and - have also been obtained.The nonaborate derivatives include -, < B9H13(NC)BH2(NC)BH3>-, -, and -.

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Product name:N(P(C6H5)3)2(1+)*B9H13(NCB(C6H5)3)(1-)=(N(P(C6H5)3)2)(B9H13(NCB(C6H5)3))

Cas No:107875-78-5

107875-78-5

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