A NOVEL LITHIUM IODIDE- PROMOTED VINYLCYCLOPROPANE-CYCLOPENTENE REARRANGEMENT: EFFICIENT SYNTHESIS OF BICYCLOOCT-6-EN-2-ONE, VERSATILE BUILDING BLOCK FOR POLYCYCLOPENTANOID NATURAL PRODUCTS

DOI: 10.1016/S0040-4039(00)84670-5

Source and publish data:

Tetrahedron Letters p. 2885 - 2888 (1986)

Update date:2022-07-30

Topics:

Authors:

Hashimoto, Sun-ichi

Shinoda, Tomohiro

Ikegami, Shiro

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Article abstract of DOI:10.1016/S0040-4039(00)84670-5

Bicyclo<3.3.0>oct-6-en-2-one, a versatile building block for polycyclopentanoid natural products, has been efficiently synthesized from 2-methoxycarbonyl-2-cyclopentenone by employing palladium- catalyzed cyclopropanation and lithium iodide- promoted viny

Full text of DOI:10.1016/S0040-4039(00)84670-5

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