Complexes of the Platinum Metals. Part 32. Synthesis and Chemistry of some Iridium Sulphonate Derivatives

DOI: 10.1039/DT9870000947

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 947 - 952 (1987)

Update date:2022-08-04

Topics:

Authors:

Harding, Alexander P.

Robinson, Stephen D.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9870000947

Sulphonic acids RSO3H (R = CF3, CH3, or C6H4CH3-p) react with mer-, , and to afford the products , , and respectively.Under more vigorous conditions the last reaction yields the bis(sulphonate) complexes .Thelability of the monodentate sulphonate ligands has been demonstrated by the substitution reactions of with a variety of neutral donor ligands.Products readily obtained in this manner include , 2 = 2,2'-bipyridyl, 1,10-phenanthroline, ethylenediamine, or o-NH2-C6H4NH2>, and trans-.Carbonylation of affords the tricarbonyl salt whereas under similar conditions the precursors (R = CH3 or C6H4CH3-p) yield the dihydride salts .Many of the complexes isolated were solvated by H-bonded molecules of sulphonic acids.Stereochemical assignments based on ¹H, ¹⁹F, and ³¹ n.m.r. data are given for all the new products reported.

Full text of DOI:10.1039/DT9870000947

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:dihydridobis(pyridine)bis(triphenylphosphine)iridium(III) trifluoromethanesulphonate

Cas No:108531-80-2

R&D Labs maybe for 108531-80-2

Amadis Chemical Co., Ltd.

website:http://www.amadischem.com

Contact:86-571-89925085

Address:Watts Cosine.No.166.Xiangmao Road.
ShanDong XinDa Chemical CO.,LTD(expird)

Contact:086-0311-87580543

Address:No.168, High Technology Development Zone Jinan Shandong China
Xuzhou Tianrun Chemical Co.,Ltd

website:http://www.tianrunchem.cn

Contact:86-516-83832636

Address:fuxing road
Goldwills Pharmaceuticals Co., Ltd.

Contact:0916-2237889 13991621155

Address:North Suburb of Hanzhong city, Shaanxi Province
Nanjing Spring & Autumn Biological Engineering Co., Ltd.

Contact:86-180510-83338

Address:Suite# 210, No. 1 BuildingNanjing Agricultural Biotechnology High-tech Entrepreneurship Center, No. 4 Tongwei Road, Xuanwu District, Nanjing,China

Relevant to this article

Mild alkaline hydrolysis of some 7-O-flavone glycosides. Application to a novel access to rutinose heptaacetate

Doi:10.1016/j.tetlet.2005.04.085
(2005)
Reactions of 1,4-pentadien-3-ones. 7. The reaction of sulfone-analogs of pentadienones with malonic esters

Doi:10.1002/ardp.19753081009
(1975)
Doi:10.1016/S0040-4039(00)72907-8
(1966)
On the cleavage of tertiary amines with ethyl chloroformate

Doi:10.1248/cpb.24.342
(1976)
Doi:10.1021/jo00879a009
(1976)
Nucleophilic and acid catalyst behavior of a protic ionic liquid in a molecular reaction media. Part 1

Doi:10.1002/poc.1501
(2009)

Article Doi