PRACTICAL WAYS FROM ALDEHYDES TO 2-CHLORO-1,1,1-TRIFLUORO-2-ALKENES AND 2-CHLORO-1,1-DIFLUORO-1-ALKEN-3-OLS

DOI: 10.1016/S0040-4039(00)84873-X

Source and publish data:

Tetrahedron Letters p. 3655 - 3658 (1986)

Update date:2022-09-26

Topics:

Authors:

Fujita, Makoto

Hiyama, Tamejiro

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Article abstract of DOI:10.1016/S0040-4039(00)84873-X

A reagent system CF3CCl3/Zn(>2 mol)/Ac2O transformed aldehydes to 2-chloro-1,1,1-trifluoro-2-alkenes exclusively, whereas CF3CCl3/Zn(>2 mol)/AlCl3(cat.) converted aldehydes into 2-chloro-1,1-difluoro-1-alken-3-ols.

Full text of DOI:10.1016/S0040-4039(00)84873-X

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