METHYLPHOSPHINYL (Dmp): A NEW PROTECTING GROUP OF TYROSINE SUITABLE FOR PEPTIDE SYNTHESIS BY USE OF BOC-AMINO ACIDS

DOI: 10.1016/S0040-4039(00)84943-6

Source and publish data:

Tetrahedron Letters p. 4181 - 4184 (1986)

Update date:2022-08-03

Topics:

Authors:

Ueki, Masaaki

Sano, Yoshiyuki

Sori, Ichiro

Shinozaki, Kozo

Oyamada,Hidekazu

Ikeda, Shigeru

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Article abstract of DOI:10.1016/S0040-4039(00)84943-6

Use of dimethylphosphinyl (Dmp) group as a side-chain phenolic OH protecting group of tyrosine in peptide synthesis was studied.The Dmp group is resistant to trifluoroacetic acid and hydrogenolysis and removed by fluoride ion or liquid HF.

Full text of DOI:10.1016/S0040-4039(00)84943-6

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