SYNTHESIS OF 1,2-CIS-LINKED GLYCOSIDES USING DIMETHYL(METHYLTHIO)SULFONIUM TRIFLATE AS PROMOTER AND THIOGLYCOSIDES AS GLYCOSYL DONORS

DOI: 10.1016/S0040-4039(00)83917-9

Source and publish data:

Tetrahedron Letters p. 3919 - 3922 (1986)

Update date:2022-07-29

Topics: Characterization Glycosidic Bond Formation Activation of the Glycosyl Donor Glycosyl acceptor Thioglycoside

Authors:

Andersson, Fredrik

Fuegedi, Peter

Garegg, Per J.

Nashed, Mina

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Article abstract of DOI:10.1016/S0040-4039(00)83917-9

Stereoselective, halide-assisted, 1,2-cis-glycosylations may be obtained using stable thioglycosides containing a non-participating 2-substituent as glycosyl donors, in the presence of dimethyl(methylthio)sulfonium triflate and tetrabutylammonium bromide

Full text of DOI:10.1016/S0040-4039(00)83917-9

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