Periselectivity in Cycloadditions to Vinylmethylketene and Structurally Related Vinylketene Imines

DOI: 10.1021/jo00391a020

Source and publish data:

Journal of Organic Chemistry p. 3289 - 3296 (1987)

Update date:2022-09-26

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Authors:

Barbaro, Gaetano

Battaglia, Arturo

Giorgianni, Patrizia

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Article abstract of DOI:10.1021/jo00391a020

The isomer distribution in cycloaddition reactions of C-vinylmethylketene and isoelectronic C-vinylketene imines, with partners of different electronic demand, has been compared.Very electrophilic reactants (TCNE, PTAD) gave, in both cases, a unique isome

Full text of DOI:10.1021/jo00391a020

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