DIRECT LITHIATION OF GLYCALS. SYNTHESIS OF C-2 BRANCHED SUGARS

DOI: 10.1016/S0040-4039(00)84896-0

Source and publish data:

Tetrahedron Letters p. 4007 - 4010 (1986)

Update date:2022-07-29

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Authors:

Schmidt, Richard R,

Kast, Juergen

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Article abstract of DOI:10.1016/S0040-4039(00)84896-0

Direct lithiation at the C-2 atom of 1-phenylsulfinyl substituted glucals 4a,b can be readily performed with LDA as indicated by reactions of different C-electrophiles.Ohenylsulfinyl group removal takes place in the aldehyde reaction products by simple th

Full text of DOI:10.1016/S0040-4039(00)84896-0

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