BIOMIMETIC SYNTHESIS OF 5α-HYDROXY-GUAIANOLIDES

DOI: 10.1016/S0040-4039(00)84640-7

Source and publish data:

Tetrahedron Letters p. 2771 - 2774 (1986)

Update date:2022-07-29

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Authors:

Gonzalez, Antonio

Galindo, Antonio

Palenzuela, Jose A.

Mansilla, Horacio

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Article abstract of DOI:10.1016/S0040-4039(00)84640-7

A 5α-hydroxy-guaianolide was synthesized biomimetically from a 5-oxo-E-1(10)-germacrenolide, the stereoselectivity of the cyclization being attributed to preferred conformation.

Full text of DOI:10.1016/S0040-4039(00)84640-7

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