Fluoride Ion Mediated Peterson of Bis(trimethylsilyl)methylimines: a Novel Synthesis of 2-Aza-1,3-dienes and N-Vinyl-β-lactams

DOI: 10.1039/c39890000072

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 72 - 74 (1989)

Update date:2022-08-04

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Authors:

Lasarte, Juan

Palomo, Claudio

Picard, Jean P.

Dunogues, Jacques

Aizpurua, Jesus M.

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Article abstract of DOI:10.1039/c39890000072

The formation of bis(trimethylsilyl)methylimines and their transformation into aza-1,3-dienes by means of a fluoride-induced catalytic Peterson alkenation is reported; when the procedure was applied to N--azetidin-2-ones, a wide range of N-vinyl derivatives were obtained in high yields.

Full text of DOI:10.1039/c39890000072

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