Chemistry Letters p. 1723 - 1726 (1986)
Update date:2022-08-03
Topics:
Hiroi, Kunio
Sato, Hiroyasu
The aluminium chloride-catalyzed acylation of α-silylallylic selenides with acid chlorides at -78 deg C produced γ-acylated vinylic selenides regioselectively. α-Silylallylic selenides in some cases underwent <1,3> shifts of the selenenyl groups by the catalysis with aluminium chloride, affording γ-silylallylic selenides.This regioselective acylation of allylic selenides provides a new route to dihydrojasmone.
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