Functionalized Oxazoles from Rhodium-Catalyzed Reaction of Dimethyl Diazomalonate with Nitriles

DOI: 10.1016/S0040-4039(00)85265-X

Source and publish data:

Tetrahedron Letters p. 5559 - 5562 (1986)

Update date:2022-07-29

Topics:

Authors:

Connell, Richard

Scavo, Frank

Helquist, Paul

Akermark, Bjoern

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Article abstract of DOI:10.1016/S0040-4039(00)85265-X

Rhodium(II) acetate catalyzes the reaction of dimethyl diazomalonate with nitriles to give 4-carbomethoxy-5-methoxy-1,3-oxazoles.Oxazole formation exceeds cyclopropane formation even in cases of conjugated and non-conjugated unsaturated nitriles.

Full text of DOI:10.1016/S0040-4039(00)85265-X

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