REACTION DE CYCLOADDITION ENTRE L'ETHOXY-1 TRIMETHYLSILYL-3 PROPYNE-1 ET LES ACETALS : SYNTHESE DE CARBETHOXY-2 TRIMETHYLSILANES ALLYLIQUES, DIENIQUES OU ENYNIQUES DIVERSEMENT SUBSTITUES

DOI: 10.1016/S0040-4039(00)85242-9

Source and publish data:

Tetrahedron Letters p. 5479 - 5482 (1986)

Update date:2022-09-26

Topics:

Authors:

Pornet, J.

Rayadh, A.

Miginiac, L.

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Article abstract of DOI:10.1016/S0040-4039(00)85242-9

In the presence of titanium tetrachloride, 1-ethoxy-3-trimethylsilyl-1-propyne easily reacts with many saturated, unsaturated or functional acetals to lead to 2-carbethoxy allylic, dienic or enynic trimethylsilanes, in a regioselective and often stereoselective way.

Full text of DOI:10.1016/S0040-4039(00)85242-9

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