Phosphine addition to pyruvoyl ligands of iron complexes: Formation of zwitterionic metallalactones

DOI: 10.1021/om800804b

Source and publish data:

Organometallics p. 216 - 224 (2009)

Update date:2022-08-05

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Authors:

Salauen Salauen

Rumin Rumin

Setifi Setifi

Triki Triki

Jaffres Jaffres

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Article abstract of DOI:10.1021/om800804b

Tertiary phosphines react, at -80 °C, with the pyruvoyl-substituted iron complex (CO)₄Fe[C(O)C(O)CH₃](CO₂CH ₃) (1) to give rise to phosphonium-substituted metallalactones fac-(CO)₃e[C(O)C(CH_{3
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Full text of DOI:10.1021/om800804b

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Product name:Fe(CO)4(C(O)C(CH₃)(P(CH₃)2C₆H₅)OCO)⁽¹⁺⁾*BF₄^(1-)=(Fe(CO)4(C(O)C(CH₃)(P(CH₃)2C₆H₅)OCO))BF₄

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