Collection of Czechoslovak Chemical Communications p. 1719 - 1730 (1992)
Update date:2022-08-04
Topics:
Vinczer, Peter
Kajtar-Peredy, Maria
Juvancz, Zoltan
Novak, Lajos
Szantay, Csaba
The synthesis of verbenyl acetate (Ia) and propionate (Ib) was inestigated by acyloxylation of α-pinene with lead(IV) acetate (LTA), lead(IV) propionate (LTP), mercury(II) acetate (MA) and iodosobenzene diacetate (IBDA) in neutral and acidic medium.The neutral medium is better for the formation of Ia and Ib, because the acidic medium helps the opening of cyclobutane ring of α-pinene.These methods can be used for large scale preparation of insect attractants to cockroach species (Blatella germanica, Blatella orientalis and Periplaneta americana).
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Doi:10.1021/jo01359a614
(1957)Doi:10.1039/c9cc04634h
(2019)Doi:10.1021/ja01171a530
(1949)Doi:10.1039/c5ra06337j
(2015)Doi:10.1002/anie.200803819
(2008)Doi:10.1016/j.ejmech.2017.11.098
(2018)