New Routes to Regioselectively Mono-Protected 1,3-Diols from Allyl and Homoallyl Alcohols via Intramolecular Hydrosilation

Article abstract of DOI:10.1246/cl.1987.171

Allyl and homoallyl alcohols are transformed into 1,3-diol derivatives, in which only the originally present hydroxy groups are regioselectively protected, by a sequence of intramolecular hydrosilation, protection, and oxidative cleavage of the carbon-sil