Tetrahedron Letters p. 6103 - 6106 (1997)
Update date:2022-08-04
Topics:
Barluenga, Jose
Sanz, Roberto
Fananas, Francisco J.
N-Allyl-N-(2-lithioallyl)aniline undergoes intramolecular carbometallation via 5-exo addition on treatment with CuCN. 2-Alkenyl 2-bromophenyl ethers rearrange to 2-(2-alkenyl)phenols by bromine-lithium exchange and further transmetallation with CuCN.
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