AN EFFICIENT SYNTHESIS OF GLYCOSYL ESTERS EXPLOITING THE MITSUNOBU REACTION.

DOI: 10.1016/S0040-4039(00)85334-4

Source and publish data:

Tetrahedron Letters p. 5813 - 5816 (1986)

Update date:2022-08-02

Topics:

Authors:

Smith III, Amos B.

Hale, Karl J.

Rivero, Ralph A.

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Article abstract of DOI:10.1016/S0040-4039(00)85334-4

The anomeric hydroxyl group of various pyranose hemiacetals can be esterified with inversion of configuration, conveniently, mildly and on large-scale using triphenylphosphine (TPP), with either diisopropylazodicarboxylate (DIAD) or diethylazodicarboxylat

Full text of DOI:10.1016/S0040-4039(00)85334-4

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Product name:Cyclohexanecarboxylic acid (2S,3R,4S,5R,6R)-4,5-diacetoxy-6-acetoxymethyl-3-((2S,3R,4S,5R,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yl ester

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