Journal of the American Chemical Society p. 6115 - 6118 (1987)
Update date:2022-09-26
Topics:
Flann, Christopher J.
Overman, Larry E.
The first enantioselective total syntheses of the natural antibiotic (+)-streptazolin (1) and its dihydro derivative 2 are described.Key steps are a stereoselective vinylsilane-terminated cyclization of a tartrate-derived N-acyliminium ion (17 -> 18) and
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