SOLVOLYTIC HYDROPEROXIDE REARRANGEMENTS V. A Stereoselective Synthesis of trans-Fused Butyrolactones.

DOI: 10.1016/S0040-4039(00)95668-5

Source and publish data:

Tetrahedron Letters p. 135 - 138 (1987)

Update date:2022-09-26

Topics:

Authors:

Ruder, Suzanne M.

Ronald, Robert C.

Lillie, Thomas S.

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Article abstract of DOI:10.1016/S0040-4039(00)95668-5

Stereoselective rearrangement of cis-5-(4-methoxybenzyl)-spiro<5,2>octan-4-ol cis-1 in acidified THF-90percent H2O2 affords 9-oxabicyclo<6.2.1>nonyl hydroperoxydes 7 and 8 which are converted to medium-ring, keto-butyrolactones 2 and 3.

Full text of DOI:10.1016/S0040-4039(00)95668-5

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