Tetrahedron Letters p. 5927 - 5930 (1986)
Update date:2022-08-03
Topics:
Degueil-Castaing, M.
Jeso, B. De
Kraus, G. A.
Landgrebe, K.
Maillard, B.
The mechanism of the formation of lactones by free radical additions of tri-n-butyltin iodoacetate to alkenes occurs through a two-step process: a homolytic addition of the ester (addition of .CH2-CO2SnBu3, iodine transfer), followed by a fast ionic cyclization with elimination of tri-n-butyltin iodide.
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Doi:10.1021/jo00051a007
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(2014)Doi:10.1021/acs.orglett.5b00190
(2015)Doi:10.1039/c3dt50781e
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