Journal of Organometallic Chemistry p. 73 - 85 (1986)
Update date:2022-08-02
Topics:
Bauer, Herbert
Beck, Wolfgang
The oxidative addition of HBF4 and C4F9SO3H to the nitrogen complex trans-(Ph3P)2Ir(N2)Cl gives the hydrido iridium(III) complexes (Ph3P)2(N2)(Cl)Ir(H)X (X-=FBF3-, OSO2C4F9-) in which the two excellent leaving groups(X- and N2) can be successively substituted by weak and strong donors (H2O, CH3OH, CH3COCH3, THF, CH3CN, CO, C2H4, PPh3; dithiocarbamate, valinate). (Ph3P)2(L)(Cl)Ir(H)FBF3 (L=CO, N2) catalyze the isomerization of 1,2-diphenyl- and phenyloxirane to diphenyl and phenyl acetaldehyde, respectively.
View MoreContact:+8613400661290
Address:No 908,Kangwan Rd, Liuyang Economic
Guangxi Nanning Guangtai Agriculture Chemical Co.,Ltd
Contact:+86-771-2311266
Address:Room703,Building12, Software Park Phase II,NO.68,Keyuan Road,Nanning City,Guangxi,China
Hefei TNJ chemical industry co.,ltd
website:https://www.tnjchem.com
Contact:+86-551-65418695
Address:B911 Xincheng Business Center, Qianshan Road, Hefei Anhui China
Zhangjiagang Jianing Import & Export Co.,Ltd.
Contact:086-512-55379012 13913607595
Address:NO.1 Guotai North Road Zhangjiagang Economic Development Zone,215600,Jiangsu,China
Shenyang Xinyihan Chemical Technology Co., Ltd.
Contact:+86-18525026267
Address:362, aigongbeijei street 23 , tiexi district,Shenyang, Liaoning, China
Doi:10.1016/S0040-4039(00)86021-9
(1983)Doi:10.1016/j.ejmech.2016.07.025
(2016)Doi:10.1016/j.tet.2008.10.096
(2009)Doi:10.1002/zaac.200700205
(2007)Doi:10.1021/jm00388a028
(1987)Doi:10.1016/S0040-4039(00)94878-0
(1985)