Asymmetric Induction in the Addition Reactions of Chiral Sulfinylallyl Anions (Ambident Nucleophiles) with Enones (Ambident Electrophiles). Ring Closure of Enol Thioether Ketones

DOI: 10.1021/jo00381a002

Source and publish data:

Journal of Organic Chemistry p. 719 - 728 (1987)

Update date:2022-07-30

Topics:

Authors:

Hua, Duy H.

Venkataraman, S.

Coulter, M. Jo

Sinai-Zingde, Gurudas

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00381a002

The regio- and stereochemical aspects of reactions of sulfinylallyl anions possessing chiral sulfur with various cyclic enones are reported.The 1,4-γ-adducts (Michael-type adducts) were obtained with excellent enantioselectivity in most cases (70-96percen

Full text of DOI:10.1021/jo00381a002

Products guided by the article

Product name:(E)--3-<3-(p-tolylsulfinyl)-2-propen-1-yl>cycloheptanone

Cas No:110366-48-8

R&D Labs maybe for 110366-48-8

Dragon Chemical Co., Ltd.

Contact:0571-

Address:zhejing
Tosta Enterprise Co., Ltd.

Contact:+86-134-5286-9121

Address:Add: Wing Tuck Commercial Centre, 177-183 Wing Lok Street, Hong Kong,
JIEJIE GROUP CO.,LTD.

Contact:+86 021-51698675

Address:1701, Jielong Plaza, No.618 Pingliang Rd, ShangHai,China
Nanjing Fayekong Chemcial Co.,Ltd(expird)

Contact:86-25-58813444

Address:Rm 1503, Unit 1, Building 5, Zijinnanyuan, Nanjing, Jiangsu, China
Hopechem Co., Ltd.

Contact:+86-20-38011066

Address:3510, Diwang Commercial Center, 5002 Shennan Rd, Shenzhen, P.R.China

Relevant to this article

Investigation of Electrostatic Interactions towards Controlling Silylation-Based Kinetic Resolutions

Doi:10.1002/ejoc.201900754
(2019)
A Simple Synthesis of 3H-λ⁵-Phosphole Derivatives from Alkyldiphenylphosphine Imines and Dimethyl Acetylenedicarboxylate

Doi:10.1039/c39860001574
(1986)
SOLID STATE PHOTOCHEMISTRY OF 2,5-CYCLOHEXADIENONES

Doi:10.1016/S0040-4020(01)81650-1
(1987)
Metallosupramolecular Cluster Assemblies based on Donor-Acceptor Type Structural Frameworks. Syntheses, Crystal Structures and Spectroscopic Properties of Novel Triosmium Alkylidyne Carbonyl Clusters bearing Remote Ferrocenyl Units as Electron Donors

Doi:10.1039/DT9950001379
(1995)
Doi:10.1016/S0040-4039(01)82730-1
()
Photochemical Heterocyclization of Functionalized Dienamines

Doi:10.1021/jo00233a017
(1987)

Article Doi