Asymmetric Induction in the Addition Reactions of Chiral Sulfinylallyl Anions (Ambident Nucleophiles) with Enones (Ambident Electrophiles). Ring Closure of Enol Thioether Ketones

DOI: 10.1021/jo00381a002

Source and publish data:

Journal of Organic Chemistry p. 719 - 728 (1987)

Update date:2022-07-30

Topics:

Authors:

Hua, Duy H.

Venkataraman, S.

Coulter, M. Jo

Sinai-Zingde, Gurudas

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Article abstract of DOI:10.1021/jo00381a002

The regio- and stereochemical aspects of reactions of sulfinylallyl anions possessing chiral sulfur with various cyclic enones are reported.The 1,4-γ-adducts (Michael-type adducts) were obtained with excellent enantioselectivity in most cases (70-96percen

Full text of DOI:10.1021/jo00381a002

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