STEREOSELECTIVE ACYCLIC SYNTHESIS VIA ALLYLMETALS: THREO VICINAL DIOLS FROM E- AND Z-γ-ALKOXYALLYLTINS AND ALDEHYDES

DOI: 10.1016/S0040-4039(00)95670-3

Source and publish data:

Tetrahedron Letters p. 143 - 146 (1987)

Update date:2022-07-31

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Authors:

Koreeda, Masato

Tanaka, Yoshio

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Article abstract of DOI:10.1016/S0040-4039(00)95670-3

Both E- and Z-γ-alkoxyallyltins stereoselectively add to aldehydes in the presence of BF3*OEt2 at -78 deg C in CH2Cl2 to produce the threo (or syn) vicinal diol monoalkyl ether unit.

Full text of DOI:10.1016/S0040-4039(00)95670-3

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